Pirolisis Ampas Tebu (Saccharum officinarum Linn): Pengaruh Suhu terhadap Yield dan Karakteristik Produk

Siti Jamilatun, Joko Pitoyo, Zulia Arifah, Shinta Amelia, Alfian Maarif

Abstract


Potensi pemanfaatan biomassa sebagai sumber energi dan senyawa kimia yang bernilai tinggi terus dikembangkan. Ampas tebu adalah biomassa dari residu pengolahan tanaman tebu (Saccharum officinarum Linn) yang pemanfaatannya belum maksimal. Pengolahan ampas tebu dengan pirolisis akan menghasilkan produk cair (organic phase dan water phase), padat (biochar) dan gas. Pirolisis dilakukan pada suhu 300, 400, 500, 550 dan 600°C didalam reactor fixed-bed. Produk cair berupa organic dan water phase dengan yield maksimum diperoleh masing-masing pada 500°C dan 550°C. Hasil uji Gas Cromatography and Mass Spectroscopy (GC-MS) untuk water phase diperoleh senyawa levoglukosan (78 % area) yang sangat potensial diolah menjadi ethanol. Potensi biochar dapat dikembangkan untuk material maju dan banyak keperluan dengan surface area dengan kisaran 180,3-198,0 m2/g, average pore size pada kisaran 1,217-4,230 nm, total pore volume pada kisaran 0,001-0,122 cc/g. Kandungan gas hasil pirolisis ampas tebu adalah CO2 dan CH4. Pada suhu 300°C hanya terbentuk CO2, selanjutnya pada 400 ke 600°C CH4 meningkat tajam pada kisaran 95,04 ke 98,10%.


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References


Asadullah, M., Rahman, M.A., Ali, M.M., Rahman, M.S., Motin, M.A., Sultan, M.B., Alam, M.R. (2007). Production of bio-oil from fixed bed pyrolysis of bagasse. Fuel 86, 2514–2520.

Bonelli, P.R., Buonomo, E.L., Cukierman, A.L. (2007). Pyrolysis of sugarcane bagasse and co-pyrolysis with an Argentinean subbituminous coal. Energy Sources Part A. 29, 731–740.

Bridgwater, A.V., Czernik, S., Piskorz, J. (2008). The status of biomass fast pyrolysis. In: Bridgwater, A.V. (Ed.), Fast Pyrolysis of Biomass: A Handbook, 2. CPL Press Liberty House, Newbury, UK, pp. 1–22.

Demirbas, A., Arin, G. (2002). An overview of biomass pyrolysis. Energy Sources 24, 471–482.

De Wild, P.J., Reith, H., and Heeres, H.J. (2011). Biomass pyrolysis for chemicals. Biofuels, 2 (2), 185 – 208.

Dhyani, V. & Bhaskar, T. (2018). A comprehensive review on the pyrolysis of lignocellulosic biomass. Renewable Energy. 129 (2018) 695-716.

David, G.F., Justo, O.R., Pereza, V.H., Garcia-Perez, M. (2018). Thermochemical conversion of sugarcane bagasse by fast pyrolysis: High yield of levoglucosan production. Journal of Analytical and Applied Pyrolysis 133(2018). 246–253.

Food and Agriculture Organization of the United Nations (FAO). FAO Global Statistical Yearbook, FAO Regional Statistical Yearbooks. FAO; 2021.

Gao, W., Chen, K., Xiang, Z., Yang, F., Zeng, J., Li, J., Yang, R., Rao, G., Tao, H. (2013). Kinetic study on pyrolysis of tobacco residues from the cigarette industry. Ind. Crops Prod. 44, 152–157.

Islam, M.R., Haniu, H., Islam, M.N., Uddin, M.S. (2010). Thermochemical conversion of sugarcane bagasse into bio-crude oils by fluidized-bed pyrolysis technology. J. Therm. Sci. Technol. 5, 11–23.

Jamilatun, S., Budiman, A., Anggorowati, H., Yuliestyan, A., Pradana, YS, Budhijanto, Rochmadi. (2019). Ex-Situ Catalytic Upgrading of Spirulina platensis Oil Residue Using Silica Alumina Catalyst. International Journal of Renewable Energy Research, 9(4), 1733-1740, 2019.

Kan, T., Strezov, V., Evans, T.J., 2016. Lignocellulosic biomass pyrolysis: a review of product properties and effects of pyrolysis parameters. Renew. Sustain. Energy Rev. 57, 1126–1140.

Kapatel, D.V., Rotliwala, Y.C. (2022). Influence of sugarcane bagasse addition in co-pyrolysis with sewage sludge on the thermogravimetric characteristics and study of kinetic. Materials Today: Proceedings. 57 (2022) 1776–1780.

Lee, Y., Park, J., Ryu, C., Gang, K.S., Yang, W., Park, Y.K., Jung, J., Hyun, S. (2013). Comparison of biochar properties from biomass residues produced by slow pyrolysis at 500 ◦C. Bioresour. Technol. 148, 196–201.

Mc.Kendry, P., 2002. Energy production from biomass (part 1): overview of biomass. Bioresour. Technol. 83, 37–46.

Mantilla, S.V., Gauthier-Maradei, P., Gil, P.Á., Cárdenas, S.T. (2014). Comparative study of bio-oil production from sugarcane bagasse and palm empty fruit bunch: yield optimization and bio-oil characterization. J. Anal. Appl. Pyrolysis 108, 284–294.

Montoya, J.I., Valdés, C., Chejne, F., Gómez, C.A., Blanco, A., Marrugo, G., Osorio, J., Castillo, E., Aristóbulo, J., Acero, J. (2015). Bio-oil production from Colombian bagasse by fast pyrolysis in a fluidized bed: an experimental study. J. Anal. Appl. Pyrolysis 112, 379–387.

Miranda, N.T., Motta, I.L., Filho, R.M., Wolf Maciel, M.R. (2021). Sugarcane bagasse pyrolysis: A review of operating conditions and products properties. Renewable and Sustainable Energy Reviews. 149 (2021) 111394.

Ordonez-Loza, J., Chejne, F., Abdul Jameel, A.G., Telalovic, S., Arrieta, A.A., Sarathy, A. (2021). An investigation into the pyrolysis and oxidation of bio-oil from sugarcane bagasse: Kinetics and evolved gases using TGA-FTIR. Journal of Environmental Chemical Engineering 9 (2021) 106144

Parihar, M.F., Kamil, M., Goyal, H.B., Gupta, A.K., Bhatnagar, A.K., 2007. An experimental study on pyrolysis of biomass. Process Saf. Environ. Prot. 85, 458–465.

Parthasarathy, P., Narayanan, S. (2015). Effect of combined slow pyrolysis and steam gasification of sugarcane bagasse on hydrogen generation. Korean J. Chem. Eng. 32, 2236–2246.

Rezaei, P.S., Shafaghat, H., Daud, W.M.A.W., 2014. Production of green aromatics and olefins by catalytic cracking of oxygenate compounds derived from biomass pyrolysis: a review. Appl. Catal. A 469, 490–511.

Rodier, L. Bilba, K., Onésippe, C., Arsène, M.A. (2019). Utilization of bio-biochars from sugarcane bagasse pyrolysis in cement-based composites. Industrial Crops & Products. 141(2019)111731.

Savou, V., Grause, Kumagai, S., Saito, Y., Kameda, T., Yoshioka, T. (2019). Pyrolysis of sugarcane bagasse pretreated with sulfuric acid. Journal of the Energy Institute. 92 (2019) 1149-1157

Varma, A.K. & Mondal. P. (2017). Pyrolysis of sugarcane bagasse in semi batch reactor: Effects of process parameters on product yields and characterization of products. Industrial Crops and Products. 95 (2017) 704–717.


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