POTENSI ZEOLIT ALAM BAYAH BANTEN SEBAGAI KATALIS HETEROGEN PADA PEMBUATAN BIODIESEL SECARA TRANSESTERIFIKASI

Rudi Hartono, Anondho Wijanarko, Heri Hermansyah

Abstract


Zeolit alam bayah banten (ZABBrht) mengandung modernit dan klipnotilonit yang berpontensi untuk dibuat katalis heterogen. untuk penghasil bioiesel. Pertama Zeolit di hancurkan dengan menggunakan palu untuk mendapatkan ukuran (50 – 60) mesh, keringkan pada suhu 1100C selama 24 jam di dalam Oven. Impregnasi menggunakan KOH dalam 100 ml aquadest selama 2 jam pada suhu 600C, keringkan dalam oven kembali selama 24 jam pada suhu 1100C, pisahkan dengan menggunkan pompa vakum, kalsinasi pada suhu 4500c selama 3 jam. Katalis heterogen ini ramah lingkungan dan mudah dipisahkan dan dapat digunakan kembali. biodiesel yang dihasilkan pada suhu 600C selama 2 jam dengan perbandingan rasio methanol dan minyak jelantah 1:7. Hasil biodieselnya adalah : 87,8% (75 gram KOH/100mL). Hasil Biodiesel di analisa dengan GC Ester content dan katalis termodifikasi dikarakterisasi dengan menggunakan FTIR, SEM-EDX, XRD

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References


Al-Jammal, Noor, Al-Hamamre, Zayed, & Alnaief, Mohammad. (2016). Manufacturing of zeolite based catalyst from zeolite tuft for biodiesel production from waste sunflower oil.

Renewable Energy, 93(Supplement C), 449-459. doi: https://doi.org/10.1016/j.renene.2016.03 .018

Chen, Ying-Chen, Lin, Dai-Ying, & Chen, Bing-Hung. (2017). Transesterification of acid soybean oil for biodiesel production using lithium metasilicate catalyst prepared from diatomite. Journal of the Taiwan Institute of Chemical Engineers, 79, 31-36.

Đặng, Tấn-Hiệp, Chen, Bing-Hung, & Lee, Duu-Jong. (2017). Optimization of biodiesel production from transesterification of triolein using zeolite LTA catalysts synthesized from kaolin clay. Journal of the Taiwan Institute of Chemical Engineers, 79, 14- 22. doi: https://doi.org/10.1016/j.jtice.2017.03.0 09

Fereidooni, Leila, & Mehrpooya, Mehdi. (2017). Experimental assessment of electrolysis method in production of biodiesel from waste cooking oil using zeolite/chitosan catalyst with a focus on waste biorefinery. Energy Conversion and Management, 147(Supplement C), 145-154. doi: https://doi.org/10.1016/j.enconman.201 7.05.051

Hartono R, Rusdi, Anondho Wijanarko, Heri Hermansah, 2016, Pembuatan Biodiesel Dari Minyak Dedak Padi Dengan Proses Katalis Homogen Secara Asam dan Katalis Hetergogen Secara Basa, Prosiding Seminar Nasional Sains dan Teknologi Fakultas Teknik Universitas Muhammadiyah Jakarta 2015, ISSN :2407-1846, e-ISSN : 2460-8416.

Hartono, R., Wijanarko, A., & Hermansyah, H. (2018). Synthesis of biodiesel using local natural zeolite as heterogeneous anion exchange catalyst. IOP Conference Series: Materials Science and Engineering, 345(1), 012002.

Ma, Yingqun, Wang, Qunhui, Sun, Xiaohong, Wu, Chuanfu, & Gao, Zhen. (2017). Kinetics studies of biodiesel production from waste cooking oil using FeCl3- modified resin as heterogeneous catalyst. Renewable Energy, 107(Supplement C), 522-530. doi: https://doi.org/10.1016/j.renene.2017.02 .007

Manadee, Saowanee, Sophiphun, Onsulang, Osakoo, Nattawut, Supamathanon, Natkanin, Kidkhunthod, Pinit, Chanlek, Narong, . . . Prayoonpokarach, Sanchai. (2017). Identification of potassium phase in catalysts supported on zeolite NaX and performance in transesterification of Jatropha seed oil. Fuel Processing Technology, 156, 62- 67. doi: https://doi.org/10.1016/j.fuproc.2016.09 .023

Volli, Vikranth, & Purkait, M. K. (2015). Selective preparation of zeolite X and A from flyash and its use as catalyst for biodiesel production. Journal of Hazardous Materials, 297, 101-111. doi: http://dx.doi.org/10.1016/j.jhazmat.2015 .04.066

Zhang, Yue, Wong, Wing-Tak, & Yung, Ka-Fu. (2013). One-step production of biodiesel from rice bran oil catalyzed by chlorosulfonic acid modified zirconia< i> via simultaneous esterification and transesterification. Bioresource technology, 147, 59-64.


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