Characterization of Catalytic Converter Made from Chrome-Plated Copper Plate Catalyst for Gasoline Motors

RM Bagus Irawan, Achmad Sholecan, M Subri, Antonius Pantomy

Abstract


This study characterizes copper (Cu) and chrome-plated copper (Cu-Cr) catalyst materials used in catalytic converters for gasoline engines. The objective is to investigate morphological and compositional changes resulting from exhaust gas emission testing. Scanning Electron Microscopy (SEM) coupled with Energy Dispersive X-ray Spectroscopy (EDX) was employed for microstructural analysis of the catalyst materials. The research examines morphological changes in Cu and Cu-Cr catalysts before and after exhaust gas emission testing, along with elemental composition alterations. Results indicate that exhaust gas exposure significantly alters the morphology and composition of both catalyst types. Morphologically, Cu catalyst particles originally flat with fine grains exhibited rougher, uneven surfaces with random grain formations and porosity post-testing. Similarly, Cu-Cr catalyst surfaces transformed from smooth to uneven, marked by darkened spots. Compositionally, Cu catalysts initially consisting of five elements (Cu 82.92%, O 5.96%, C 10.22%, Cl 0.60%, Si 0.29%) changed to include eight elements (Cu 70.65%, O 12.89%, C 12.85%, Cl 0.66%, Si 0.27%, N 1.74%, Al 0.27%, S 0.67%). Cu-Cr catalysts initially composed of three elements (Ni 87.65%, Cr 10.50%, C 1.85%) evolved to five elements (Ni 86.01%, Cr 6.56%, O 5.70%, O 1.42%, S 0.71%). These findings underscore the transformative effects of exhaust gas exposure on catalyst materials, influencing both their morphology and elemental composition, crucial for enhancing catalytic converter performance and durability in automotive applications.

Keywords


Catalytic Converter; Cu Catalyst; Cu-Cr Catalyst; SEM-EDX

Full Text:

PDF

References


Catalyst Handbook. Wolfe Scientific Book, London - England, Springer - Verlag New York Inc, 1970.

Dowden et al, "Catalytic Handbook," Verlag New York, Inc, 1970.

B. Irawan, "Rancang Bangun Catalytric Converter dengan Material Substrat Tembaga (Cu) untuk Mereduksi Emisi Gas CO," J. Traksi, 2004.

Warju, "Pengaruh Penggunaan catalytic Converter Tembaga berlapis Mangan Terhadap Kadar Polutan Motor Bensin Empat langkah," Institut Teknologi Surabaya, 2006.

Obert, Internal Combustion Engine and Air Pollution, 3rd ed. Harper & Row, Publisher, Inc., New York, 1973.

Liyod, Handbook of Industrial Catalysts, Fundamental and Applied Catalysis, 2011.

Mattey, "Dennis Dowden and the Development of Catalytic Science," Technology Review. [Online]. Available: www.technology.mattey.com, 2014.

B. Irawan, "Pengaruh Letak Pemasangan Catalytic Converter Terhadap Keluaran Emisi Gas Carbon Monoksida dan Hidro Carbon Motor Bensin," Maj. Ilm. Tek. Mesin, Traksi, 2007.

H. Heisler, Advanced Engine Tecnology, Hodder Headline Group, London, 1995.

J. B. Heywood, Internal Combustion Engine Fundamentals, International ed. Graw-Hill, Inc., New York, 1988.

B. Irawan, "Karakterisasi Katalis Tembaga Pada Catalytic Converter Untuk Mengurangi Emisi Gas Carbon Monoksida Motor Bensin," Maj. Ilm. Tek. Mesin, Traksi, 2014.

B. Irawan, "Karakterisasi Catalytic Converter Motor Bensin Berbahan Katalis Tembaga Lapis Mangan," Sem. Nas. Tek. Kimia Undip, 2016.

B. Irawan, "Pengaruh Perubahan Putaran Mesin Terhadap Temperatur Catalytic Converter Berbahan Logam Transisi Tembaga Mangan," Sitek J., 2021.

B. Irawan, "Effect Of Number Of Transition Metal Catalyst Cell Manganese Catalytic Converter On Exhaust Basis Emission Output Carbon Monoxide Motor Gasoline," Sintek J., 2022.

H. Abdullah, "Pembuatan dan Karakterisasi serta Aplikasi Katalik Konverter untuk Filter Gas Buang Kenderaan Bermotor Berbahan Bakar Premium," J. USU, 2012.

M. L. Marlisa, "Uji Karakteristik Nanopartikel Magnetit (Fe3o4) Menggunakan X-Ray Diffraction Dan SEM," 2017. [Online]. Available: http://repositori.uin-alauddin.ac.id/9216/1/

H. Singh, "Performance Analysis Of Catalytic Converter," J. Emerg. Technol. Innov. Res., 2018.

K. D. P., "Design And Development Of Automotive Catalytic Converter Using Non-Nobel Catalyst For The Reduction Of Exhaust Emission: A Review," 2022. [Online]. Available: https://doi.org/10.1016/j.matpr.2022.03.350

K. S. L. Kuen, "Fine Structural Characterization Of Noble Metals In Washcoat Of Motorcycle Three-Way Converter Catalysts," J. Environ. Chem. Eng., 2023. [Online]. Available: https://www.sciencedirect.com/journal/journal-of-environmental-chemical-engineering




DOI: https://doi.org/10.24853/sintek.18.1.31-37

Refbacks

  • There are currently no refbacks.


Copyright (c) 2024 SINTEK JURNAL: Jurnal Ilmiah Teknik Mesin

Powered by Puskom-UMJ